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CML696

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CML696
physical Organic Chemistry
Credits 3
Structure 3-0-0
Pre-requisites
Overlaps

CML696 : physical Organic Chemistry

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Overlap with: CML743 Introduction to Molecular Orbital theory, frontier Orbitals and orbital mixing; Details of Reactive intermediates; Correlation between the perturbations to a chemical bond and potential energy; Simple rate laws; Arrhenius equation and Eyring equation, Transition State theory. Kinetics vs Thermodynamic control; Experimental investigation of reaction mechanisms and short lived intermediates; The kinetic Isotope Effect; Reaction trajectories: Cross-over experiments; Characterisation of short lived intermediates; Examples of reactive species and their behavior Supramolecular chemistry. Electron transfer reactions. Organic photochemical transformation (including catalysis).